International Journal of Scientific Research and Engineering Development

International Journal of Scientific Research and Engineering Development


( International Peer Reviewed Open Access Journal ) ISSN [ Online ] : 2581 - 7175

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A Case Study on Excess Thermodynamic properties and Molecular Interactions in Binary liquid Mixture



    International Journal of Scientific Research and Engineering Development (IJSRED)

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Published Issue : Volume-3 Issue-6
Year of Publication : 2020
Unique Identification Number : IJSRED-V3I6P72
Authors : Dr. K. G. Neerajakshi
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Abstract :

Experimentally measured data for viscosity and refractive index of binary mixture are reported in this research paper for various compositions for three different temperatures at atmospheric pressure. Modified Ubbelholde viscometer and Abbe-3L Refractometer were used for experimental measurements. Deviation in molar refraction (ΔR) and deviation in viscosity (Δη) w.r.t composition have been calculated from the experimental data. ‘Grunberg and Nissan’ equation and Herric’s Correlation were used to correlate the viscosity data. Excess thermodynamic properties were fitted to Redlich-Kister equation. Coefficients and standard deviations, hence obtained are reported. Variation in Excess Thermodynamic properties for the mixture have been discussed in terms of intermolecular interactions.